I would not just default to exfat because it is “newer,” it does have compatibility issues on non-windows systems. The implementations differ wildly.
Veracrypt. Make a file on your disk.
Don’t want a storage file?
Make 2 partitions, put veracrypt portable exe on the first normal storage partition. (fat32 is likely ideal here) Second partition formatted with veracrypt.
Set aside a few weekends and mess around distro hopping. Think of it as a small scientific study. Use what you determine to be the most comfortable with.
I suggest being clever in your partitioning keeping /home and any other areas personal to their own partition if not their own disks. If you want to experiment you lose nothing by wiping / and installing something else. Also, you should decide on an effective backup strategy.